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Today, there are more ways to take photos of the underwater world than anyone could have imagined at the start of the millennia, thanks to ever-improving designs for aquatic cameras. On one hand, they have provided illuminating views of life in the seas. But on the other hand, these devices have inundated marine biologists with mountains of visual data that have become incredibly tedious and time-consuming to sort through.
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Vehicle emissions represent one of the most important air pollution sources in most urban areas, and elevated concentrations of pollutants found near major roads have been associated with many adverse health impacts. To understand these impacts, exposure estimates should reflect the spatial and temporal patterns observed for traffic-related air pollutants. This paper evaluates the spatial resolution and zonal systems required to estimate accurately intraurban and near-road exposures of traffic-related air pollutants. The analyses use the detailed information assembled for a large (800 km2) area centered on Detroit, Michigan, USA. Concentrations of nitrogen oxides (NOx) due to vehicle emissions were estimated using hourly traffic volumes and speeds on 9,700 links representing all but minor roads in the city, the MOVES2010 emission model, the RLINE dispersion model, local meteorological data, a temporal resolution of 1 hr, and spatial resolution as low as 10 m. Model estimates were joined with the corresponding shape files to estimate residential exposures for 700,000 individuals at property parcel, census block, census tract, and ZIP code levels. We evaluate joining methods, the spatial resolution needed to meet specific error criteria, and the extent of exposure misclassification. To portray traffic-related air pollutant exposure, raster or inverse distance-weighted interpolations are superior to nearest neighbor approaches, and interpolations between receptors and points of interest should not exceed about 40 m near major roads, and 100 m at larger distances. For census tracts and ZIP codes, average exposures are overestimated since few individuals live very near major roads, the range of concentrations is compressed, most exposures are misclassified, and high concentrations near roads are entirely omitted. While smaller zones improve performance considerably, even block-level data can misclassify many individuals. To estimate exposures and impacts of traffic
High strength aluminum alloys are known as hard to weld alloys due to their high hot crack susceptibility. However, they have high potential for applications in light weight constructions of automotive industry and therefore it is needed to increase weldability. One major issue is the high hot cracking susceptibility. Vaporization during laser beam welding leads to a change of concentration of the volatile elements magnesium and zinc. Hence, solidification range of the weld and therefore hot cracking susceptibility changes. Additionally, different welding velocities lead to changed solidification conditions with certain influence on hot cracking. This paper discusses the influence of energy per unit length during laser beam welding of AA 7075 on the change of element concentration in the weld seam and the resulting influence on hot cracking susceptibility. Therefore EDS-measurements of weld seams generated with different velocities are performed to determine the change of element concentration. These quantitative data is used to numerically calculate the solidification range in order to evaluate its influence on the hot cracking susceptibility. Besides that, relative hot crack length and mechanical properties are measured. The results increase knowledge about welding of high strength aluminum alloy AA 7075 and hence support further developing of the welding process.
Poly (AA co PVP)/PGS (PAPP) composite adsorbent was prepared by radical polymerization from Acrylic acid (AA), Polyvinylpyrrolidone (PVP) and Palygorskite (PGS), using N,N-methylenebisacrylamide (MBA) as cross-linker and potassium persulfate (KPS) as initiator. The PAPP was characterized with Fourier transform infrared (FT-IR), thermogravimetric analysis (TG), scanning electron microscope (SEM) and transmission electron microscopy (TEM). PAPP was used as adsorbent for the removal of methylene blue from aqueous solutions. The influences of pH, adsorption temperature and adsorption time on the adsorption properties of the composite to the dye were also investigated. Meanwhile, the adsorption rate data and adsorption equilibrium date were analyzed based on the pseudo-first-order and pseudo-second-order kinetic model, Langmuir and Freundlich isotherm models, respectively. The results indicating that the kinetic behavior better fit with the pseudo-second-order kinetic model. The maximum equilibrium adsorption capacity (q(m)) is 1815 mg/g at 289 K. The isotherm behavior can be explained by the Langmuir isotherm models. The activation energy was also evaluated for the removal of methylene blue onto PAPP. These results demonstrate that this composite material could be used as a good adsorbent for the removal of cationic dyes from wastewater. Copyright © 2014 Elsevier Inc. All rights reserved. 2b1af7f3a8